Efficiency Promises versus Broken Promises
The promise of CIGS cells is that high-efficiency cells can be achieved using less than 1/100th the semiconducting materials required for silicon-based PV cells. At the same time, CIGS cells present a challenge because four-layers of semiconducting material (copper, indium, gallium and di-selenide, or in some cases sulfur) must be deposited correctly to create an efficient cell. (Image on right is a Global Solar CIGS cell)
Correction: An astute reader points out that I got this a bit wrong. “The CIGS in the solar cells is not a four-layer stack (and more particularly, di-selenide is not a material per se) Rather, it is a chemical compound, a crystal where one copper atom, one indium or gallium atom and two selenium atoms (hence di-selenide) make up each basic unit. You can talk about the challenge of getting four-layer structures right, but then it’s the structure back contact–absorber–buffer–window.”
I stand corrected. On with the story…
Every photovoltaic-themed PowerPoint ever presented since the birth of the sun includes the NREL PV efficiency chart. It’s tradition to include it, so here it is. The NREL chart bears some of the blame for the billions of dollars of VC investment (and public company investment) into CIGS development. Here’s a list of the top five recipients of VC funding in the CIGS/CIS universe.
Firm                  VC Received
Solyndra            $600M+
Nanosolar          $500M
MiaSolé              $300M
SoloPower          $235M+
SulfurCell           $165M+
That’s $1.8 billion dollars right there and the figure easily exceeds $2.3 billion when one counts the remaining CIGS players.
Some of that irrational VC exuberance is due to the hero experiments charted by NREL. Its champion numbers show a potential efficiency for CIGS of 19.9 percent—exceeding CdTe’s 16.5 percent, equal to polycrystalline silicon, and approaching the neighborhood of single crystal silicon’s 24.5 percent.
Those numbers are encouraging to investors as it means that there exists a thin film solution that can potentially disruptively displace the incumbent material, silicon, in a high growth $20 billion dollar market.
However, according to an industry source, that pioneering CIGS work was performed in ultra-high vacuum (UHV) in a tool with 10 E10 (10 range) vacuum, a pristine vacuum environment. How much performance does one give up when relaxing the vacuum environment for the sake of manufacturing?
CIGS efficiency is sacrificed by relaxing the deposition conditions for the sake of manufacturing:
Bottom line here is that real-life CIGS efficiencies, when manufactured in anything less than a pristine vacuum environment are never going to come close to the incumbent silicon efficiencies. The following chart bears that out.
CIGS Firm                     Claimed Efficiency for Cell or Module
Ascent Solar                      9.6%*
Daystar                              10%-11.5%
Global Solar                   10.2%*
HelioVolt                       12.2%
MiaSolé                             10.2%?
NanoSolar                     9-10%?
Shell Solar                        12.8%*
Solyndra                        NA
Wuerth Solar                  13.0%
* confirmed by NREL
Despite theoretical CIGS efficiencies approaching 20 percent—it appears that the best this crop of CIGS firms is going to be able to produce is in the 10 percent to 12 percent range. That’s still better than CdTe and low efficiency is certainly not preventing First Solar from ramping up to GW scale.
But efficiency is not going to be a significant differentiator amongst the CIGS rivals.
One other caution about these efficiency claims: Even with an NREL confirmation—most of these figures represent best efforts on small samples, not production averages on large areas over time.
This is an excerpt from the February issue of the Greentech Innovations Report. This issue focuses on CIGS manufacturing and also reports on every greentech funding in January 2009. Upcoming issues focus on ocean power, algae, and energy storage.
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Greentech Media's Green Light blog covers the full-scope of the greentech world, while expanding the range of our daily news reporting with brief and insightful blog posts from our Greentech Media editors, GTM Research analysts and numerous guest bloggers.
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